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Home > Products >  Titanium tetraisopropanolateCAS NO.: 546-68-9

Titanium tetraisopropanolateCAS NO.: 546-68-9 CAS NO.546-68-9

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Keywords

  • Titanium tetraisopropanolate
  • TTIP
  • 99.5% Titanium tetraisopropanolate

Quick Details

  • ProName: Titanium tetraisopropanolateCAS NO.: 5...
  • CasNo: 546-68-9
  • Molecular Formula: C12H28O4Ti
  • Appearance: colourless liquid
  • Application: Catalyst and Auxiliary
  • DeliveryTime: In stock
  • PackAge: Aluminium Foil Bag and Paper Drum
  • Port: China main port
  • ProductionCapacity: 10000 Gram/Day
  • Purity: 99%
  • Storage: Room temperature
  • Transportation: By sea or by air
  • LimitNum: 1 Kilogram
  • Grade: Industrial Grade,Food Grade,Pharma Gra...
  • first class: 1-10

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Details

Hazard Codes  Xi,F
Risk Statements  10-36-36/37/38-11-67
Safety Statements  16-26-36/37/39-7/9
RIDADR  UN 2413 3/PG 3
WGK Germany  2
RTECS  NT8060000
21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29051900
Hazardous Substances Data 546-68-9(Hazardous Substances Data)
MSDS Information
Provider Language
Titanium(IV) isopropoxide English
ACROS English
SigmaAldrich English
ALFA English
 
Titanium tetraisopropanolate Usage And Synthesis
Reactions
  • Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
  • Useful for diastereoselective reduction of alpha-fluoroketones.
  • Catalyzes the asymmetric allylation of ketones.
  • Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
  • Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
  • Catalytic intramolecular formal [3+2] cycloaddition.
  • Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents
Chemical Properties colourless to light yellow liquid
Uses Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
General Description A water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water and . Flash point 66°F. Vapors heavier than air.
Air & Water Reactions Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity Profile Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health Hazard Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Purification Methods Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]

 

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