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Home > Products >  Tris(2-ethylhexyl) phosphate CAS NO.78-42-2

Tris(2-ethylhexyl) phosphate CAS NO.78-42-2 CAS NO.78-42-2

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Keywords

  • Tris(2-ethylhexyl) phosphate
  • PHOSPHORIC ACID TRIS(2-ETHYLHEXYL) ESTER
  • 1-Hexanol, 2-Ethyl-, phosphate

Quick Details

  • ProName: Tris(2-ethylhexyl) phosphate CAS NO.78...
  • CasNo: 78-42-2
  • Molecular Formula: C24H51O4P
  • Appearance: colourless viscous liquid
  • Application: Synthetic fragrances
  • DeliveryTime: In stock
  • PackAge: drum
  • Port: China main port
  • ProductionCapacity: 10000 Metric Ton/Month
  • Purity: 99%
  • Storage: Room temperature
  • Transportation: By Sea/Air/DHL
  • LimitNum: 1 Kilogram
  • first class: 1-10

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Details

Tris(2-ethylhexyl) phosphate Basic information
Product Name: Tris(2-ethylhexyl) phosphate
Synonyms: PHOSPHORIC ACID TRIS(2-ETHYLHEXYL) ESTER;PHOSPHORIC ACID TRIOCTYL ESTER;TRIS(2-ETHYLHEXYL) PHOSPHATE;TRI(2-ETHYLHEXYL)PHOSPHATE;TRIOCTYL PHOSPHATE;'TRIOCTYL' PHOSPHATE;1-Hexanol, 2-Ethyl-, phosphate;2-ethyl-1-hexanophosphate
CAS: 78-42-2
MF: C24H51O4P
MW: 434.63
EINECS: 201-116-6
Product Categories: solvent;Building Blocks;Chemical Synthesis;Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds;Organics;Functional Materials;Phosphates (Plasticizer);Plasticizer
Mol File: 78-42-2.mol
	Tris(2-ethylhexyl) phosphate Structure
 
Tris(2-ethylhexyl) phosphate Chemical Properties
Melting point  -70°C
Boiling point  215 °C4 mm Hg(lit.)
density  0.92 g/mL at 20 °C(lit.)
vapor pressure  2.1 mm Hg ( 20 °C)
refractive index  n20/D 1.444(lit.)
Fp  >230 °F
storage temp.  Store below +30°C.
solubility  <0.001g/l
form  Liquid
Specific Gravity 0.93
PH 7 (H2O, 20℃)
Water Solubility  <0.1 g/100 mL at 18 ºC
BRN  1715839
CAS DataBase Reference 78-42-2(CAS DataBase Reference)
NIST Chemistry Reference 2-Ethylhexanol phosphate (3:1)(78-42-2)
EPA Substance Registry System Tris(2-ethylhexyl) phosphate (78-42-2)
 
Safety Information
Hazard Codes  Xi
Risk Statements  38
Safety Statements  23-43-24/25
WGK Germany  2
RTECS  MP0770000
Autoignition Temperature 370 °C
TSCA  Yes
HS Code  29190090
Hazardous Substances Data 78-42-2(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 37000 mg/kg LD50 dermal Rabbit 20000 mg/kg
MSDS Information
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Tris(2-ethylhexyl) phosphate English
SigmaAldrich English
ALFA English
 
Tris(2-ethylhexyl) phosphate Usage And Synthesis
Chemical Properties Tris(2-ethylhexyl) phosphate, a clear, viscous liquid, is used as a component of vinyl stabilizers, grease additives, and flame-proofing compositions; however, it is used primarily as a plasticizer for vinyl plastic and synthetic rubber compounds.
Tris(2-ethylhexyl) phosphate
Tris(2-ethylhexyl) phosphate has been employed as a specialty flameretardant plasticizer for vinyl compositions where low temperature flexibility is critical, eg, in military tarpaulins. It can be included in blends with general purpose plasticizers such as phthalate esters to improve low temperature flexibility.
Uses Tris(2-ethylhexyl) Phosphate is used as a phosphorous flame retardant. Used as a plasticizer in the preparation of a new potentiometric membrane sensor.
Uses Solvent, antifoaming agent, plasticizer.
General Description Clear colorless to pale yellow liquid with a slight sharp odor. Insoluble in water; Soluble in alcohol, acetone, and ether. Combustible.
Reactivity Profile Tris(2-ethylhexyl) phosphate is incompatible with oxidizing materials. Tris(2-ethylhexyl) phosphate may soften or deteriorate certain plastics and elastomers. Tris(2-ethylhexyl) phosphate is incompatible with cellulose acetate and cellulose acetate butyrate.
Hazard Toxic by ingestion and inhalation.
Purification Methods TEHP, in an equal volume of diethyl ether, is shaken with aqueous 5% HCl, and the organic phase is filtered to remove traces of pyridine (used as a solvent during manufacture) as its hydrochloride. This layer is shaken with aqueous Na2CO3, then water, and the ether is distilled off at room temperature. The ester is then filtered, dried for 12hours at 100o/15mm, and again filtered, then shaken intermittently for 2days with activated alumina (100g/L). It is decanted through a fine sintered-glass disc (with exclusion of moisture), and distilled under vacuum. [French & Muggleton J Chem Soc 5064 1957.] *Benzene can be used as a solvent (to give 0.4M solution) instead of ether. IR ( ): 1702, 1701, 481 and 478cm -1 [Bellamy & Becker J Chem Soc 475 1952]. The uranyl nitrate salt is purified by partial crystallisation from hexane [Siddall & Dukes J Am Chem Soc 81 790 1959, Siddall J Am Chem Soc 81 4176 1959]. [Beilstein 1 IV 1786.]

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